Feed aggregator

To investigate the combined impacts of anthropogenic and biogenic emissions on the formation of secondary organic aerosols (SOA), SOA molecular tracers, their corresponding volatile organic compound precursors, and other air pollutants were measured online during the winter and summer seasons of 2022 in an industrial city, Zibo, China. The results indicate that the average concentrations of SOA tracers were 16.1 ± 9.8 ng m−3 in winter and 99.4 ± 57.2 ng m−3 in summer. During winter, anthropogenic SOA (ASOA, the sum of SOA derived from naphthalene and mono-aromatic volatile organic compounds) dominated, whereas isoprene SOA (SOAI) prevailed in summer. Correlation analysis between SO4 2− and both SOAI and high-order monoterpene SOA tracers (SOAM-H) (R = 0.46–0.72, p < 0.001) revealed that higher aerosol acidity facilitated the formation of SOAI and SOAM-H, with SO2 emissions playing a significant role in leading to higher acidity. Most biogenic SOA (BSOA) tracers exhibited a significant positive correlation with NO3 −, particularly in winter, implying the remarkable influence of NO x emissions on BSOA formation. The levels of BSOA tracers increased with NH3, indicating that NH3 can enhance the formation of BSOA. In summer, SOA formation correlated with O x (O x  = O3 + NO2), indicating the substantial impact of atmospheric oxidizing capacity on SOA formation. During winter, aerosol liquid water content (ALWC) correlated well with SOAI tracers (i.e., 3-hydroxyglutaric acid (3-HGA) and 3-hydroxy-4,4-dimethylglutaric acid (3-HDMGA)), and 2,3-dihydroxy-4-oxopentanoic acid (DHOPA) (R > 0.5, p < 0.001), indicating the important contribution of aqueous-phase formation of SOA. These findings underscore the significant role of anthropogenic pollutant emissions in the formation of ASOA and BSOA in urban environments.

The plasmasphere accounts for the majority of the mass of Earth's magnetosphere and contains most of the cold ion (1 eV) population. The plasmasphere is extremely dynamic, undergoing a constant cycle of erosion and refilling. In this paper we perform a statistical study of erosion and refilling rates using 6 years of data from the Van Allen Probes from the beginning of 2013 through the end of 2018. Using in-situ density measurements derived from the upper hybrid resonance line, we create global maps of the erosion and refilling rates over a wide range of L shells and local times. Sorting the data by L shell, magnetic local time, and distance to the plasmapause, we characterize the absolute and relative rates of erosion and refilling during a variety of geomagnetic conditions. We also examine three case studies of geomagnetic storms and compare their density evolutions during the recovery period. Our results are in agreement with refilling rates found by previous statistical studies using different methods, but somewhat lower than many of the case studies reported. We find median erosion rates of 164, 83, and 43 cm−3/day and refilling rates of 87, 42, and 27 cm−3/day at L = 3, 4 and 5, respectively when Kp ≤ ${\le} $ 3. We also find little local time dependence for both erosion and refilling rates.

We study how the normal stiffness and the permeability of a realistic rough fracture at the field scale are linked and evolve during its closure up to the percolation threshold. We base our approach on a well-established self-affine geometric model for fracture roughness, which has proven to be a relevant proxy from laboratory to multi-kilometer scales. We explore its implications for fracture apertures in reservoir-scale open channels. We build our approach on a finite element model using the MOOSE/GOLEM framework and conduct numerical flow-through experiments in a 256×256× $256\times 256\times $ 256 m3 ${\mathrm{m}}^{3}$ granite reservoir hosting a single, partially sealed fracture under variable normal loading conditions and undrained conditions. Navier-Stokes flow is solved in the embedded 3-dimensional rough fracture, and Darcy flow is solved in the surrounding poroelastic matrix. We study the evolution of the mechanical stiffness and fluid permeability of the fracture-rock system during fracture closure including mechanisms that impact the contact surface geometry like asperity yield and deposit of fracture-filling material in the open space of the rough fracture. The largely observed stiffness characteristic is shown to be related to the self-affine property of the fracture surface. A strong anisotropy of the fracture permeability is evidenced when the fluid percolation thresholds are exceeded in two orthogonal directions of the imposed pressure gradient. We propose a unifying physically based law for the evolution of stiffness and permeability in the form of an exponential increase in stiffness as permeability decreases.

Volcanic eruptions and wildfires can impact stratospheric chemistry. We apply tracer-tracer correlations to satellite data from Atmospheric Chemistry Experiment—Fourier Transform Spectrometer and the Halogen Occultation Experiment at 68 hPa to consistently compare the chemical impact on HCl after multiple wildfires and volcanic eruptions of different magnitudes. The 2020 Australian New Year (ANY) fire displayed an order of magnitude less stratospheric aerosol extinction than the 1991 Pinatubo eruption, but showed similar large changes in mid-latitude lower stratosphere HCl. While the mid-latitude aerosol loadings from the 2015 Calbuco and 2022 Hunga volcanic eruptions were similar to the ANY fire, little impact on HCl occurred. The 2009 Australian Black Saturday fire and 2021 smoke remaining from 2020 yield small HCl changes, at the edge of the detection method. These observed contrasts across events highlight greater reactivity for smoke versus volcanic aerosols at warm temperatures.

Atlantic Meridional Overturning Circulation (AMOC) variability originates from a large number of interacting processes with multiple time scales, with dominant processes dependent on both the latitude and timescale of interest. Here, we isolate the optimal atmospheric modes driving climate-relevant decadal AMOC variability using a novel approach combining dynamical and statistical attribution (dynamics-weighted principal component, or DPC analysis). We find that for both the subpolar (55°N) and subtropical (25°N) AMOC, the most effective independent mode of heat flux forcing closely resembles the North Atlantic Oscillation, and drives meridionally coherent AMOC anomalies through western boundary density anomalies. Conversely, established modes of wind stress variability possess limited quantitative similarity to the optimal wind stress patterns, which generate low-frequency AMOC fluctuations by rearranging the ocean buoyancy field. We demonstrate (by running a modified version of the ECCOv4r4 state estimate) that most AMOC variability on decadal time scales can be explained by the DPCs.

Lightning is the severest threaten to safe operation of wind turbines. In this letter, the authors present the first altitude-triggered lightning experiment involving an elevated 12 m-long wind turbine blade placed on the ground. A total of 50 precursors with amplitude over 62.9 A were observed through measurements of channel-base current, fast electric field, and optical data. The air gap with around 3–5 m has been bridged between the wire's lower extremity and the metal blade tip during ascending of the rocket and it is observed to be luminous by slow framing rate camera. The precursors are classified into three groups, namely bipolar pulses, unipolar pulses, and group pulses. Excluding the precursors preceding the initial stage and M-components at the late-time of the initial stage, five stages are classified. In the first stage, the current remains limited at a relatively small value, while the electric field exhibited a slow rising behavior with positive polarity. In the second stage, the current starts to increase, and the electric field rapidly intensifies due to the accumulating charge, and the wire is assumed to experience an explosion. In the third stage, the reconnection process occurs. The current is characterized by a peak value of 1.45 kA with 10%–90% risetime of 10.4 μs. The electric fields suffer from notable decrease and are characterized by a microsecond-scale V-shape pulse. The current cutoff is quite short that almost not found. In the fourth step, the current is characterized by superimposed pulses. The final stage is the channel darkening.

Subthermocline eddies (SEs) influencing ocean circulation are progressively known, yet their extensive impact on the western Pacific undercurrent system remains largely unexplored and, in some regions, often underestimated. Okubo-Weiss parameter analysis reveals a distinctive meridional pattern of cyclonic and anticyclonic SE distribution in the interior western Pacific basin that aligns with zonally elongated mean flows. These westward-propagating SEs play a pivotal role in regulating the formation of zonal undercurrents, particularly off-equatorial regions, through the convergence of eddy potential vorticity flux. Along the Pacific western boundary region, anticyclonic SEs typically enhance (reverse) the velocity of boundary currents flowing northward (southward), primarily through barotropic energy conversion, while cyclonic SEs do the opposite. To summarize, we provide a schematic map of the circulation system in the western Pacific and emphasize the interconnected framework of undercurrents, particularly in relation to SEs.

We develop a 3D full waveform inversion (FWI) method based on dynamic time warping (DTW) to address the issue of cycle-skipping, which can prohibit the convergence of conventional FWI methods. DTW globally compares data samples at different time steps in 2D matrices against the time shifts of waveforms. We introduce the concept of shape descriptors into softDTW, creating a soft-shapeDTW objective function within our waveform inversion process to improve alignment accuracy. Additionally, including constraints from Sakoe-Chiba bands in the inversion further enhances efficiency and overall performance. A synthetic test has shown that the soft-shapeDTW inversion outperforms conventional waveform inversions in overcoming the cycle-skipping challenges that arise from poor initial models. This method was applied to fit observed seismograms to reveal western Yunnan's crustal structure. Seismic waveforms were recorded by 88 broadband stations from 10 local earthquakes, which were then denoised using a continuous wavelet transform method. Generalized cut and paste waveform inversions were used to determine the source parameters of these seismic events. Our inversion well-aligned various seismic phases in the selected time windows of seismograms, and the resolved velocity models well associate with local geological structure. Results suggest that the soft-shapeDTW inversion offers a robust alternative to FWI, reducing the reliance on accurate starting models.

The 2022 eruption at Mauna Loa, Hawai'i, marked the first extrusive activity from the volcano after 38 years of quiescence. The eruption was preceded by several years of seismic unrest in the vicinity of the volcano's summit. Characterizing the structure and dynamics of seismogenic features within Mauna Loa during this pre-eruptive interval may provide insights into how pre- and co-eruptive processes manifest seismically at the volcano. In particular, the extent to which seismicity may be used to forecast the location and timing of future eruptions is unclear. To address these questions, we construct a catalog of relocated seismicity on Mauna Loa spanning 2011–2023. Our earthquake locations image complex, sub-kilometer-scale seismogenic structures in the caldera and southwest rift zone. We additionally identify a set of streaks of seismicity in the volcano's northwest flank that are radially oriented about the summit. Using a rate-and-state friction model for earthquake occurrences, we demonstrate that the seismicity rate in this region can be modeled as a function of the stressing history caused by magma accumulation beneath the summit. Finally, we observe a mid-2019 step change in the seismicity rate in the Ka'oiki region that may have altered the stress state of the northeast rift zone in the three years before the eruption. Our observations provide a framework for interpreting future seismic unrest at Mauna Loa.

Mid-latitude auroras are conventionally generated during intense magnetic storms. However, mid-latitude auroras were observed by naked eyes at Beijing China (39°N, 116°E) unusually during a moderate storm event on 1 December 2023 with the minimum Sym-H index only ∼ ${\sim} $ −120 nT. This study combines conjugative in-site and ground-based observations to analyze the auroras and underlying physical processes. Results indicate that both electron and proton auroras appeared at low latitudes. Electron auroras predominantly arise from low-energy electron precipitation, but proton auroras may be explained by energetic tens of keV proton precipitation. Pc1/EMIC waves are observed at low latitudes in the ionosphere, potentially accounting for mid-latitude proton auroras. Downward field-aligned currents (FACs) are also detected at low latitudes, producing significant magnetic perturbations. This study reveals the underlying ionospheric responses to the mid-latitude auroras to understand potential reasons for observing aurora at such mid-latitudes during a moderate storm.

The South China Sea is a typical marginal sea characterized by the presence of numerous seamounts. However, the effect of seamounts on the air-sea CO2 flux has not yet been well studied. In September 2021, the air-sea CO2 flux was measured directly using eddy covariance (EC), and discrete waterside sampling was conducted. The results indicate that the northern South China Sea is a source of atmospheric CO2. Furthermore, EC measurements show that the seamount emits CO2 at an average rate of 0.34 mmol m−2 hr−1, nearly double that of non-seamount areas. We suggest that the upwelling around the seamount transports deep water rich in dissolved inorganic carbon to the upper ocean, increasing the partial pressure of CO2 there. In addition, the increase in nutrients caused by the upwelling would increase the concentration of chlorophyll-a, resulting in a productive area that emits CO2.

In areas of induced seismicity, earthquakes can be triggered by stress changes due to fluid injection and static deformation from fault slip. Here we present a method to distinguish between injection-driven and earthquake-driven triggering of induced seismicity by combining a calibrated, fully coupled, poroelastic stress model of wastewater injection with interpretation of a machine learning algorithm trained on both earthquake catalog and modeled stress features. We investigate seismicity from Paradox Valley, Colorado as an ideal test case: a single, high-pressure injector that has induced thousands of earthquakes since 1991. Using feature importance analysis, we find that injection-driven earthquakes are approximately 22± $\pm $5% of the total catalog but act as background events that can trigger subsequent aftershocks. Injection-driven events also have distinct spatiotemporal clustering properties with a larger b-value, closer proximity to the well, and earlier occurrence in the injection history. Generalization of our technique can help characterize triggering processes in other regions where induced seismicity occurs.

We estimate the global impact of storms on the global structure and dynamics of the night side plasma sheet from observations by the NASA mission Time History of Events and Macroscale Interactions during Substorms (THEMIS). We focus on an intense storm occurring in December 2015 triggered by interplanetary coronal mass ejections (ICMEs). It starts with a storm sudden commencement (SSC) phase (SYM-H ∼ ${\sim} $ +50 nT) followed by a growth phase (SYM-H ∼ ${\sim} $ −188 nT at the minimum) and then a long recovery phase lasting several days. We investigate THEMIS observations when the spacecraft were located in the midnight sector of the plasma sheet at distances typically between 8 and 13 Earth's radii. It is found that the plasma sheet has been globally compressed up to a value of about ∼> ${\sim} > $4 nPa during the SSC and main phases, that is, 8 times larger than its value during the quiet phase before the event. This compression occurs during periods of high dynamic pressure in the ICME (20 nPa) about one order of magnitude larger than its value in the pristine solar wind. We infer a global increase of the lobe magnetic field from 30 to 100 nT, confirmed by THEMIS data just outside the plasma sheet. During the SSC and main phases, the plasma sheet is found thinner by a factor of 2 relative to its thickness at quiet times, while the Tsyganenko T96 magnetic field model shows very stretched magnetic field lines from inner magnetospheric regions toward the night side. During the recovery phase, whereas the interplanetary pressure has dropped off, the plasma sheet tends to gradually recover its quiet phase characteristics (pressure, thickness, magnetic configuration, etc.) during a long recovery phase of several days.

The understanding of the velocity structure and basement morphology within the basin is crucial for seismic hazard mitigation and the study of basin evolution. To explore the intricate structure of the Binchuan Basin in western Yunnan, China, we deployed a linear dense array in the northern region of the Binchuan Basin, with inter-station distance ranging from 50 to 100 m. We propose a novel receiver function processing workflow. Initially, we extracted coherent receiver functions based on the dense array, followed by a inversion of basement morphology, S-wave velocities, and sedimentary layer's average V p /V s ratio jointly with frequency-dependent teleseismic apparent shear velocity and receiver function waveforms. The results show that S-wave velocity anomalies correspond to the unconsolidated sediments. The thickness of the sedimentary layer ranges from ∼0.5 to ∼0.75 km. The basement morphology suggests the basin is controlled by normal faults. Additionally, intra-basin faults displayed higher fault displacement to length ratios (∼0.27) than most isolated normal faults (10−3–10−1), which may result from accumulated fault displacement due to interactions between fault segments. These results emphasize the significant role of N–S trending intra-basin faults in basin evolution, suggesting that micro-block rotations and transitional movements within the Northwestern Yunnan Rift Zone are primary mechanisms shaping the Binchuan Basin. We further proposed a multi-stage model for the evolution of the Binchuan Basin. The robustness testing validates that the proposed processing flow is an effective approach to comprehensively image the basin velocity structure and the basement morphology.

This study uses a unique combination of geostationary and low-Earth orbiting satellite-based lightning and precipitation observations, respectively, to examine the evolution of deep convection during the tropical cyclone (TC) lifecycle. The study spans the 2018–2021 Atlantic Basin hurricane seasons and is unique as it provides the first known analysis of total lightning (intra-cloud and cloud-to-ground) observed in TCs through their extratropical transition and post-tropical cyclone (PTC) phases. We consider the TC lifecycle stage, geographic location (e.g., land, coast, and ocean), shear strength, and quadrant relative to the storm motion and environmental shear vectors. Total lightning maxima are found in the forward right quadrant relative to storm motion and downshear of the TC center, consistent with previous studies using mainly cloud-to-ground lightning. Increasing environmental shear focuses the lightning maxima to the downshear right quadrant with respect to the shear vector in tropical storm phases. Vertical profiles of radar reflectivity from the Global Precipitation Measurement mission show that super-electrically active convective precipitation features (>75 flashes) within the PTC phase of TCs have deeper mixed phase depths and higher reflectivity at −10°C than other phases, indicating the presence of more intense convection. Differences in the net convective behavior observed throughout TC evolution manifest in both the TC-scale frequency of lightning-producing cells and the intensity variations amongst individual convective cells. The combination of continuous lightning observations and precipitation snapshots improves our understanding of convective-scale processes in TCs, especially in PTC phases, as they traverse the tropics and mid-latitudes.

Earth possesses a Poincaré mode called Free Core Nutation (FCN) due to the misalignment of the rotation axes of the mantle and fluid outer core. FCN is the primary signal in the observations of Celestial Pole Offsets (CPO) and maintained by geophysical mechanisms that are yet to be understood. Earlier studies suggested an origin in Atmospheric Angular Momentum (AAM)—and to a lesser degree Oceanic Angular Momentum (OAM)—but discrepancies between these geophysical excitations and the geodetic (CPO-based) excitation were too large to reach definite conclusions. Here we use newly calculated, 3-hourly AAM and OAM series for the 1994–2022 period, in conjunction with the latest CPO series from the International Earth Rotation and Reference Systems Service (IERS 20 C04 series), to demonstrate a markedly lower power ratio (∼ ${\sim} $4.6) of geophysical over geodetic excitation at the FCN frequency compared to previous works (ratio ∼ ${\sim} $10). Among all excitation sources, the AAM pressure term exhibits the highest coherence (0.56) and correlation (0.48) with the geodetic excitation, whereas the coherence with OAM is smaller by a factor of 3. Similar analyses using existing angular momentum series give comparable, albeit smaller coherence and correlation results. We attribute the relevant AAM pressure term signal to Northern Hemispheric landmasses and further show consistent temporal variations in the amplitude of geophysical and geodetic excitations around the FCN band. Our results thus corroborate evidence for large-scale atmospheric mass redistribution to be the main cause of continuous FCN excitation.

Secondary organic aerosol (SOA) formed through the atmospheric transformation of organic vapors constitutes a significant portion of fine particulate matter or PM2.5. While recent laboratory studies underscore the importance of intermediate-volatility organic compounds (IVOCs) as key precursors to SOA, field observations that recognize the role of both volatile organic compounds (VOCs) and IVOCs in SOA formation remain scarce. In this study, we conducted concurrent measurements of VOCs and IVOCs in ambient air at urban and suburban sites in Guangzhou during a PM2.5 pollution event in winter 2021. The results reveal that between 12:00–15:00 local time, the photochemically adjusted initial concentrations of VOCs at both sites were approximately 7 times higher than that of IVOCs. However, the SOA formation potential (SOAFP) of primary hydrocarbon IVOCs exceeded that of VOCs by over 3–4 times. Receptor modeling results further indicated that while ship emissions contributed to less than 10% of the C2–C22 primary hydrocarbons concentration (VOCs + primary carbonaceous IVOCs), they accounted for the most significant source (approximately 40%) of SOA formation. This study highlights the substantial role of IVOCs in SOA formation and emphasizes the importance of future PM2.5 pollution control measures targeting major IVOCs contributors, such as ship emissions in harbor cities.

We investigated the crustal radial anisotropy in the eastern South China Block (ESCB) with the F-J multimodal ambient noise tomography. Well corresponding to widespread mid-crustal low-velocity zones in the VSV ${V}_{SV}$ model, a pronounced mid-crustal channel of positive radial anisotropy is revealed. In the Cathaysia Block, it may origin from sub-horizontally aligned quartz induced by extension and correspond to the phase transition of α $\alpha $ to β $\beta $ quartz. In other areas, while, it may be relevant to other well-aligned minerals. This positive mid-crustal radial anisotropy channel not only provides the solid evidence for dominative extensional deformation since late Mesozoic, but also may indicate an important detachment surface, contributing much to the early Mesozoic magmatism in the ESCB.

No abstract is available for this article.

The properties of the first kilometers of the Martian atmospheric Planetary Boundary Layer have until now been measured by only a few instruments and probes. InSight offers an opportunity to investigate this region through seismoacoustics. On six occasions, its seismometers recorded short low-frequency waveforms, with clear dispersion between 0.4 and 4 Hz. These signals are the air-to-ground coupling of impact-generated infrasound, which propagated in an low-altitude atmospheric waveguide. Their group velocity depends on the structure of effective sound speed in the boundary layer. Here, we conduct a Bayesian inversion of effective sound speed up to 2,000 m altitude using the group velocity measured for events S0981c, S0986c and S1034a. The inverted effective sound speed profiles are in good agreement with estimates provided by the Mars Climate Database. Differences between inverted and modeled profiles can be attributed to a local wind variation in the impact→station direction, of amplitude smaller than 2 m/s.