Feed aggregator

Alternate materials for the capture and quantification of gaseous oxidized mercury in the atmosphere
Livia Lown, Sarrah M. Dunham-Cheatham, Seth N. Lyman, and Mae S. Gustin
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-50,2024
Preprint under review for AMT (discussion: open, 1 comment)
New sorbent materials are needed to preconcentrate atmospheric oxidized mercury for analysis by developing mass spectrometry methods. Chitosan, α-Al2O3, and γ-Al2O3 were tested for quantitative gaseous oxidized mercury sorption in ambient air under laboratory and field conditions. Although these materials sorbed gaseous oxidized mercury without sorbing elemental mercury, less oxidized mercury was recovered from these materials compared to cation exchange membranes.

Robust handling of extremes in quantile mapping – "Murder your darlings"
Peter Berg, Thomas Bosshard, Denica Bozhinova, Lars Bärring, Joakim Löw, Carolina Nilsson, Gustav Strandberg, Johan Södling, Johan Thuresson, Renate Wilcke, and Wei Yang
Geosci. Model Dev. Discuss., https//doi.org/10.5194/gmd-2024-98,2024
Preprint under review for GMD (discussion: open, 4 comments)
When bias adjusting climate model data using quantile mapping, one needs to prescribe what to do at the tails of the distribution, where a larger range of data is likely encountered outside the calibration period. The end result is highly dependent on the method used, and we show that one needs to exclude data in the calibration range to activate the extrapolation functionality also in that time period, else there will be discontinuities in the timeseries.

Assessing effects of climate and technology uncertainties in large natural resource allocation problems
Jevgenijs Steinbuks, Yongyang Cai, Jonas Jaegermeyr, and Thomas W. Hertel
Geosci. Model Dev., 17, 4791–4819, https://doi.org/10.5194/gmd-17-4791-2024, 2024
This paper applies a cutting-edge numerical method, SCEQ, to show how uncertain climate change and technological progress affect the future utilization of the world's scarce land resources. The paper's key insight is to illustrate how much global cropland will expand when future crop yields are unknown. The study finds the range of outcomes for land use change to be smaller when using this novel method compared to existing deterministic models. 

Abstract

Strong surface winds induced by polar lows (PLs) may affect the upper ocean. However, understanding of the oceanic responses and feedback processes associated with PLs remains insufficient, especially for observations. Using a combined analysis of satellite-based sea surface temperature (SST) and PL tracking data, we investigated the oceanic response to 380 PL passages over the Nordic Sea occurring between 1999 and 2018. Consequently, two types of oceanic responses—warming and cooling—occurred in 32% and 40% of the total occurrences, respectively. The average magnitude of SST response was approximately ±0.2 K. Significant differences in upward surface turbulent heat flux (THF) between warming and cooling response cases were found, causing a significant difference in the decay rate after maximum PL development. By analyzing changes in the state variables of the THF, we identified two different feedback processes depending on the oceanic warming/cooling response. During a warming (cooling) response, the atmosphere near the surface becomes more unstable (stable), and the turbulence of the marine atmospheric boundary layer increases (decreases), which strengthens (weakens) the ocean surface wind and decreases (increases) temperature and specific humidity. These changes contribute to increasing (decreasing) the upward THF that influences PL development. The differences between these two responses may be caused by the state of the upper ocean layer, including temperature inversion. The analysis of the in situ observations of the upper ocean supports the hypothesis that a warming response occurs when inversion is strong. This study emphasizes the importance of feedback through oceanic responses for understanding and predicting PL.

Abstract

The operation of hydropower plants leads to sudden changes in river stage and to a flow regime known as hydropeaking. Hydropeaking alters the morphology of the riverbed and water quality, and ultimately poses a risk to riverine ecosystems. While many indicators are available to quantitatively assess this problem in rivers, the impact of hydropeaking on aquifers is largely unknown and lacks of quantitative indicators. We analyze with wavelet techniques the spatial and temporal dynamics of surface water-groundwater interaction in an aquifer impacted by two differently regulated rivers. We propose four indicators to study the aquifer stress produced by hydropeaking and classify the observed groundwater head time series into weakly, moderately and highly impacted. This study opens the possibility for a quantitative assessment of the impact of hydropeaking on the groundwater ecosystem.

Abstract

Source-to-sink transfer of sediment and organic carbon (OC) is regulated by river mobility. Quantifying trends in river mobility is, however, challenging due to diverse planform morphologies (e.g., meandering, braided) and measurement methods. Here, we utilize a remote-sensing method applicable to all planform morphologies to quantify the mobility timescales of 80 rivers worldwide. Results show that, across the continuum from meandering to braided rivers, there is a systematic reduction in the timescales of channel mobility and—to a lesser extent—floodplain reworking. This leads to a decrease in the efficiency with which braided rivers rework old floodplain material compared to their meandering counterparts. Reduced floodplain reworking efficiency of braided rivers leads to smaller channel-belt areas relative to their size. Results suggest that river-mobility timescales derived from remote sensing can aid in the characterization of sediment and OC storage and transit times at a global scale.

Abstract

This study identified four patterns of regional extreme precipitation events (REPEs) in Central Asia (CA) and their crucial synoptic systems and multiscale interactions. Four patterns with distinct spatial distributions were identified in: northern Kazakhstan, southern Xinjiang, western CA, and the Tianshan Mountains. Focusing on the three most frequent REPEs, the kinetic energy (KE) cross-scale transfer from the basic-to synoptic-scale windows exhibited a zonal dipole, resulting in the development and enhancement of REPEs in northern Kazakhstan. The available potential energy (APE) cross-scale transfer exhibited opposing patterns between the upper and lower troposphere, indicating baroclinic instability in the lower troposphere and barotropic instability of the basic flow in the upper troposphere. Both mechanisms enhanced the Central Asian vortices (CAVs) in southern Xinjiang and induced REPEs. Conversely, the energy budgets exhibited baroclinic instability of the basic flow throughout the entire region when the Tianshan Mountains REPEs occurred, providing energy for prevalent CAVs.

Abstract

This study characterizes moisture source regions for wintertime precipitation across the Salt-Verde watershed and Arizona (USA) through use of convection-permitting numerical experiments. We dynamically downscale three four-month-long (i.e., December-January-February-March, or DJFM) winter periods: a representative warm (DJFM 1997–1998), cold (DJFM 1999–2000), and neutral (DJFM 2016–2017) winter, as diagnosed by the mean Sea Surface Temperature (SST) across the El Niño 3.4 region compared to a 1995 to 2019 baseline. We utilize the Weather Research and Forecasting (WRF) model with water vapor tracers (WVTs) to distinguish moisture source contributions to total precipitation across Arizona, as originating from land evapotranspiration, sea evaporation, and external advection. Analysis of our numerical experiments demonstrates that WRF is able to capture the day-to-day precipitation events across the complex terrain that is characteristic of the Salt-Verde watershed, but seasonal accumulated precipitation is consistently overestimated compared to individual station observations. The spatial distribution of wintertime monthly accumulated precipitation across Arizona is well captured by WRF, although the total amount of rainfall is overestimated in some confined areas across the highlands of Arizona. Our convection-permitting WRF experiments also demonstrate that WVT contributions to total wintertime precipitation are apportioned roughly equally between sea evaporation (contributing 45.6%) across the North America west coast and external advection (contributing 48.1%), with land evapotranspiration playing a minimal role (i.e., the remaining 6.3%). We further conduct single-domain WRF experiments at non-convection-permitting resolution and conclude that local sea evaporation, bounded by 140°W and 100°W, is the primary moisture source region to total wintertime precipitation across the Salt-Verde watershed and Arizona independent of the remote tropical SST across the El Niño 3.4 region.

Abstract

Evaporation duct anomalies are always present above various oceanic processes, and their response to ubiquitous mesoscale eddies in the Kuroshio Extension region is quantitatively analyzed for the first time in this study using a synthetic analysis method based on reanalysis data sets and eddy trajectory data sets. The results indicated that the spatial distribution of evaporation duct anomalies is characterized by a monopole pattern, mainly modulated by the amplitude of anticyclonic eddies (AEs) and by the radius of cyclonic eddies (CEs). For AEs, the coupling strength is 0.7 m (2.9 M) per meter increase in amplitude, while for CEs, the coupling strength is 0.2 m (0.6 M) per 100 km increase in radius for the average evaporation duct height anomalies (evaporation duct strength anomalies) within the radius range. The modulation of evaporation duct anomalies by eddies is further examined.

Abstract

Utilizing atmospheric temperature observed from Mars Years 33–36 by the imaging ultraviolet spectrograph (IUVS) onboard the Mars atmosphere and volatile evolution (MAVEN) and Mars climate sounder (MCS) onboard Mars Reconnaissance Orbiter (MRO), we derive the diurnal and semidiurnal thermal tides from 30 to 160 km. Vertical phase velocities of the migrating tides indicate their upward propagation above 100 km during the dust season (solar longitude, Ls 240°–300°). During the non-dust season (Ls 30°–150°), the diurnal eastward wavenumber 2 (DE2) and wavenumber 3 (DE3) tides can propagate upward from the lower atmosphere to ∼140 km. The seasonal variation of DE2 and DE3 amplitudes in the thermosphere corresponds well to their counterparts in the lower atmosphere, primarily controlled by their Hough (1, 1) modes. The upward propagation of these tides could potentially impact the vertical coupling between the Martian lower and upper atmosphere.

Abstract

We investigated velocity and anisotropic structure of the crust beneath the eastern margin of the Tibetan Plateau to better understand its deformation and evolution mechanism. We performed H-κ and Pms anisotropy analyses to obtain crustal thickness, Vp/Vs ratio, fast polarization direction, and splitting time from 711 stations, and further conducted quality control using slowness, harmonic and statistical analyses. The Songpan-Ganzi Block has a large splitting time and a fast polarization direction roughly parallel to the GPS motion and SKS fast direction. It also shows an overall high but complex distribution of Vp/Vs ratio, and large variations in crustal thickness, indicating that crustal deformation is likely caused by crustal shortening and lower crustal flow. The northern Sichuan-Yunnan Rhombic Block (SYRB) is featured by a thick crust and high Vp/Vs ratio, suggesting that the crust is likely inflated by partial melting lower crustal rocks. The subblock also exhibits a strong azimuthal anisotropy with a splitting time greater than 0.6 s. The fast polarization direction aligns with the nearly N-S extended direction and rotates clockwise in front of the Emeishan Large Igneous Province (ELIP). The observed anisotropy agrees with aligned amphibole minerals under a simple shear condition, supporting a southward lower crust flow being diverted by the ELIP. Anisotropy measurements on the southern SYRB are less robust and widely scattered, suggesting a deformation mechanism different from the northern SYRB. In addition, the southeastern margin of the Sichuan Basin shows a systematic pattern of crustal anisotropy consistent with a pure shear deformation mechanism.

Abstract

Shallow creep events provide opportunities to understand the mechanical properties and behavior of faults. However, due to physical limitations observing creep events, the precise spatio-temporal evolution of slip during creep events is not well understood. In 2023, the Superstition Hills and Imperial faults in California each experienced centimeter-scale slip events that were captured in unprecedented detail by satellite radar, sub-daily Global Navigation Satellite Systems, and creepmeters. In both cases, the slip propagated along the fault over 2–3 weeks. The Superstition Hills event propagated bilaterally away from its initiation point at average velocities of ∼9 km/day, but propagation velocities were locally much higher. The ruptures were consistent with slip from tens of meters to ∼2 km depths. These slowly propagating events reveal that the shallow crust of the Imperial Valley does not obey purely velocity-strengthening or velocity-weakening rate-and-state friction, but instead requires the consideration of fault heterogeneity or fault-frictional behaviors such as dilatant strengthening.

Abstract

The Superstition Hills Fault (SHF) exhibits a rich spectrum of slip modes, including M 6+ earthquakes, afterslip, quasi-steady creep, and both triggered and spontaneous slow slip events (SSEs). Following 13 years of quiescence, creepmeters recorded 25 mm of slip during 16–19 May 2023. Additional sub-events brought the total slip to 41 mm. The event nucleated on the northern SHF in early-May and propagated bi-laterally at rates on the order of kilometers per day. Surface offsets reveal a bi-modal slip distribution, with slip on the northern section of the fault being less localized and lower amplitude compared to the southern section. Kinematic slip models confirm systematic variations in the slip distribution along-strike and with depth and suggest that slip is largely confined to the shallow sedimentary layer. Observations and models of the 2023 SSE bear a strong similarity to previous slip episodes in 1999, 2006, and 2010, suggesting a characteristic behavior.

Abstract

The significant risk associated with fault reactivation often necessitates slip tendency analyses for effective risk assessment. However, such analyses are challenging, particularly in large areas with limited or absent reliable stress measurements and where the cost of extensive geomechanical analyses or simulations is prohibitive. In this paper, we propose a novel approach using a physics-informed neural network that integrates stress orientation and satellite displacement observations in a top-down multi-scale framework to estimate two-dimensional slip tendency analyses even in regions lacking comprehensive stress data. Our study demonstrates that velocities derived from a continental scale analysis, combined with reliable stress orientation averages, can effectively guide models at smaller scales to generate qualitative slip tendency maps. By offering customizable data selection and stress resolution options, this method presents a robust solution to address data scarcity issues, as exemplified through a case study of the South Australian Eyre Peninsula.

Abstract

The absorption of atmospheric carbon dioxide (CO2) in the Southern Ocean represents a critical component of the global oceanic carbon budget. Previous assessments of air-sea carbon flux variations and long-term trends in polar regions during winter have faced limitations due to scarce field data and the lack of ocean color satellite imagery, causing uncertainties in estimating CO2 flux estimation. This study utilized the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation satellite to construct a continuous 16-year (2006–2021) time series of sea surface partial pressure of CO2 (pCO2) in the Southern Ocean. Our findings revealed that the polar region in South Ocean acts as a carbon sink in winter, with CO2 flux of ∼30 TgC in high-latitude areas (South of 50°S). This work highlights the efficacy of active remote sensing for monitoring sea surface pCO2 and contributes insights into the dynamic carbonate systems of the Southern Ocean.

Abstract

We explore the links between elevation variability of the Antarctic Ice Sheet (AIS) and large-scale climate modes. Using multiple linear regression, we quantify the time-cumulative effects of El Niño Southern Oscillation (ENSO) and the Southern Annular Mode (SAM) on gridded AIS elevations. Cumulative ENSO and SAM explain a median of 29% of the partial variance and up to 85% in some coastal areas. After spatial smoothing, these signals have high spatial correlation with those from GRACE gravimetry (r∼ = 0.65 each). Much of the signal is removed by a firn densification model but inter-model differences exist especially for ENSO. At the lower parts of the Thwaites and Pine Island glaciers, near their grounding line, we find the Amundsen Sea Low (ASL) explains ∼90% of the observed elevation variability. There, modeled firn effects explain only a small fraction of the variability, suggesting significant height changes could be a response to climatological ice-dynamics.

Abstract

We construct a high-resolution shear-wave velocity (VS) model for the uppermost 100 m using ambient noise tomography near the West Antarctic Ice Sheet Divide camp. This is achieved via joint inversion of Rayleigh wave phase velocity and H/V ratio, whose signal-to-noise ratios are boosted by three-station interferometry and phase-matched filtering, respectively. The VS shows a steep increase (0.04–0.9 km/s) in the top 5 m, with sharp interfaces at ∼8–12 m, followed by a gradual increase (1.2–1.8 km/s) between 10 and 45 m depth, and to 2 km/s at ∼65 m. The compressional-wave velocity and empirically-obtained density profile compares well with the results from Herglotz–Wiechert inversion of diving waves in active-source shot experiments and ice core analysis. Our approach offers a tool to characterize high-resolution properties of the firn and shallow ice column, which helps to infer the physical properties of deeper ice sheets, thereby contributes to improved understanding of Earth's cryosphere.

Abstract

Using high-resolution data from the Magnetospheric Multiscale mission, an electron-only reconnection current sheet is found between two successive dipolarization fronts (DFs). The electron-only reconnection occurs between the northward component of the magnetic field of the flux pileup region (FPR) of the first DF (DF1) and the southward component of the magnetic dip of the second DF (DF2). The faster DF2 compresses the FPR of DF1, which constitutes an anti-parallel topology and reduces the thickness of the current sheet. Further analysis shows that the current sheet is unstable to the electron tearing instability, which may power the onset of the reconnection. Our results suggest that these two DFs may merge into one by the reconnection, which sheds light on the evolution of DFs during their earthward propagation.

Abstract

The magnetic fields of terrestrial planets are created by core convection. Molten silicate mantles could also generate magnetic fields through their convective motion, known as a silicate dynamo. Recent computational studies have suggested that silicate melts may exhibit high electrical conductivity (EC) at temperatures above 4000 K due to strong electronic conduction, which could activate a silicate dynamo. We determined the EC of dense molten MgSiO3 up to 71 GPa and 4490 K by static compression experiments. It jumped by one order of magnitude upon melting, but 57(27) S/m at 4490 K is much lower than previous predictions, suggesting that molten MgSiO3 carries charge via ions rather than predicted electronic conduction. Nevertheless, the strong temperature dependence of the ionic conductivity found in this study suggests that super-Earths’ hotter magma ocean with larger-scale convection could power a dynamo that drives magnetic fields, which plays key roles in sustaining planetary surface environments.

Abstract

An unseasonal equatorial plasma bubble (EPB) event occurred in the East/Southeast Asian sector during the geomagnetic storm on 1 December 2023, causing strong amplitude scintillations from equatorial to middle latitudes. Based on the observations from multiple instruments over a large latitudinal and longitudinal region, the spatial features of the super EPB were investigated. The EPB developed vertically at a fast rising speed ∼470 m/s over the magnetic equator and extended to a very high middle latitude more than 40°N, despite that the storm intensity was not very strong with the minimum SYM-H index −132 nT. In the zonal direction, the super EPB covered over a specific region ∼95–140°E, where the local sunset roughly coincided with southward turning of interplanetary magnetic field (IMF) Bz component. Before the onset of the super EPB, significant upward plasma drift up to ∼110 m/s was observed over the magnetic equator, which could amplify the growth rate of Rayleigh-Taylor instability and lead to the generation of the super EPB. The significant drift was likely caused by eastward penetration electric field (PEF) due to sharp southward turning of IMF Bz. The local time of storm onset and duration of IMF Bz southward turning during the storm main phase may partly determine the onset region and zonal coverage of the EPB.